An Undecanuclear FeIII Single-Molecule Magnet

Ayuk M. Ako; Valeriu Mereacre; Yanhua Lan; Wolfgang Wernsdorfer; Rodolphe Clerac; Christopher E. Anson; Annie K. Powell

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An Undecanuclear FeIII Single-Molecule Magnet

机译：不可核的FeIII单分子磁体

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The undecanuclear complex in [FeIII 11(μ4-O)3(μ3-O)4(L)3(μ- O2CCMe3)12]Cl 3 5MeCN has been synthesized and characterized by single-crystal X-ray crystallography. Mossbauer spectroscopy and bulk susceptibility studies reveal that the complex has an S = 13/2 spin ground state and exhibits single-molecule-magnet behavior.

机译：合成了[FeIII 11（μ4-O）3（μ3-O）4（L）3（μ-O2CCMe3）12] Cl 3 5MeCN中的无核络合物，并通过单晶X射线晶体学对其进行了表征。 Mossbauer光谱学和大量磁化率研究表明，该复合物具有S = 13/2的自旋基态，并表现出单分子磁体行为。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2010年第1期|共3页
作者
Ayuk M. Ako; Valeriu Mereacre; Yanhua Lan; Wolfgang Wernsdorfer; Rodolphe Clerac; Christopher E. Anson; Annie K. Powell;
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正文语种 eng
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single-molecule-magnet; Undecanuclear; crystallography;

机译：单分子磁体;未清核;晶体学;

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1. An Undecanuclear FeIII Single-Molecule Magnet [J] . Ayuk M. Ako, Valeriu Mereacre, Yanhua Lan, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2010,第1期

机译：不可核的FeIII单分子磁体
2. Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [FeIII(acac₂-trien)]+ and [FeIII(sal₂-trien)]+ molecules [J] . Alexandre Abhervé, Samuel Ma?as-Valero, Miguel Clemente-León, Chemical science . 2015,第8期

机译：石墨烯相关的磁性材料：基于双金属苯甲酸酯配合物并插入[Fe III （acac _{2 -trien）] + 的二维层状磁体的微机械剥离和[Fe III （sal _{2 -trien）] + 分子}}
3. Low coordinated mononuclear erbium(III) single-molecule magnets with C-3v symmetry: a method for altering single-molecule magnet properties by incorporating hard and soft donors [J] . Zhang Haitao, Nakanishi Ryo, Katoh Keiichi, Dalton transactions: An international journal of inorganic chemistry . 2018,第2期

机译：具有C-3V对称性的低协调单核铒（III）单分子磁体：通过掺入硬质和软供体来改变单分子磁体特性的方法
4. Catalytic Stibine Dehydrocoupling versus Antimony-ligated Dysprosium Single-Molecule Magnets [C] . Fu-Sheng Guo, Benjamin M. Day, Thomas Pugh Rare Earth Research Conference . 2019

机译：催化词汇脱水耦合与锑脱羟镝单分子磁铁
5. Highly Conducting Single-Molecule Magnets with d-π Interactions [D] . Shen Yongbing 2019

机译：具有d-π相互作用的高导电单分子磁体
6. Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted FeIII(acac2-trien)+ and FeIII(sal2-trien)+ molecules [O] . Alexandre Abhervé, Samuel Mañas-Valero, Miguel Clemente-León, 2015

机译：石墨烯相关的磁性材料：基于双金属苯甲酸酯配合物的FeIII（acac2-trien） +和FeIII（sal2-trien） +分子的二维层状磁体的微机械剥离
7. Heptanuclear FeIII6CrIII3+ Complexes Experimentally Studied by Means of Magnetometry, X-ray Diffraction, XAS, XMCD and Spin-Polarized Electron Spectroscopy in Cross-Comparison with MnIII6CrIII3+ Single-Molecule Magnets [O] . Niklas Dohmeier, Andreas Helmstedt, Norbert Müller, 2016

机译：通过磁体测定，X射线衍射，XAS，XMCD和旋转偏振电子光谱与MNIII6CRIII 3 +单分子磁铁进行实验研究，通过磁体，X射线衍射，XAS，XAS，XMC和旋转偏振电子光谱进行实验研究

An Undecanuclear FeIII Single-Molecule Magnet

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