Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes

Kaspi AW; Yahav-Levi A; Goldberg I; Vigalok A

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes

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Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes

机译：二氟化氙诱导的芳基碘还原消除：一种简单的二氟钯（II）配合物

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摘要

Palladium(II) aryliodo complexes bearing chelating diphosphine ligands react with XeF2, giving iodoarene and rare palladium(II) difluoro complexes. The reaction is general with regard to the aryl group, with even C6F5-I undergoing facile reductive elimination from a Pd center.

机译：带有螯合二膦配体的钯（II）芳基碘配合物与XeF2反应，生成碘芳烃和稀有的钯（II）二氟配合物。关于芳基，该反应是一般的，甚至C 6 F 5 -I也从Pd中心经历容易的还原消除。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics 》 |2008年第1期| 共3页
作者
Kaspi AW; Yahav-Levi A; Goldberg I; Vigalok A;
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正文语种 eng
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关键词
ARYLPALLADIUM(II) HALIDE-COMPLEXES; COUPLING REACTIONS; PALLADIUM(II); PLATINUM(II); STABILITY; BONDS; PD;

机译：卤化钯芳烃（II）;偶联反应;钯（II）;铂（II）;稳定性;键;PD;

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1. Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes [J] . Kaspi AW, Yahav-Levi A, Goldberg I, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008 ,第1期

机译：二氟化氙诱导的芳基碘还原消除：一种简单的二氟钯（II）配合物
2. A DFT Study on the Conversion of Aryl Iodides to Alkyl Iodides: Reductive Elimination of R-I from Alkylpalladium Iodide Complexes with Accessible -Hydrogens [J] . Hao Wei, Wei Junnian, Chi Yue, Chemistry: A European journal . 2016 ,第10期

机译：DFT研究芳基碘化物向烷基碘化物的转化：烷基钯碘化物配合物与氢的还原消除R-1
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4. Spectroscopic Studies on Fe(II) and Fe(III) Complexes of 5-Aryl Azo Substituted lH-pyrimidine-2,4-dione [C] . Vidya V G, S S Meena, Pramod Bhatt, RAM 2013 . 2013

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5. Oxidative addition of aryl halides and sulfonates to palladium(0), and reductive elimination of aryl halides and diaryl ethers from palladium(II): Mechanistic investigations and synthetic applications. [D] . Roy, Amy Helen. 2003

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6. Concerted aryl-sulfur reductive elimination from PNP pincer-supported Co(iii) and subsequent Co(i)/Co(iii) comproportionation [O] . Bryan J. Foley, Chandra Mouli Palit, Nattamai Bhuvanesh, 2020

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7. Xenon Difluoride Induced Aryl Iodide Reductive Elimination: a Simple Access to Difluoropalladium(II) Complexes [O] . -1

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8. Reductive Elimination of H-H, H-CH3, and CH3-CH3 from Bis(Phosphine)Platinum(II), - Palladium(II), and -Nickel(II) Complexes: A Theoretical Study Using the SCF-X alpha-SW Method [R] . Balazs, A. C., Johnson, K. H., Whitesides, G. M. 1981

机译：从双（膦）铂（II）， - 钯（II）和-Nickel（II）配合物中还原消除H-H，H-CH3和CH3-CH3：使用sCF-Xα-sW方法的理论研究

Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes

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