Substituent Effects on the Structures of Silver Complexes with Monoazatrithia-12-Crown-4 Ethers Bearing Substituted Aromatic Rings

摘要

New 4'-methoxybenzyl-,4'-methylbenzyl-,benzyl-,3',5'-difluorobenzyl-,3',5'-dichlorobenzyl-,and 4'-nitrobenzyl-armed monoazatrithia-12-crown-4 ethers were prepared by the reductive amination of monoazatrithia-12-crown-4 with the appropriate benzenecarbaldehyde in the presence of NaBH(0Ac)3.Cold electrospray ionization mass spectrometry and X-ray crystallography show that silver complexes with armed monoazatrithia-12-crown-4 ethers bearing aromatic side arms with electron-donating groups or electron-withdrawing groups are coordination polymers and trimers,respectively.The structures of the silver complexes were strongly dependent on the strength of the CH...pi interactions,which are controlled by substituent effects on the aromatic side arms.