A thioketene complex of molybdenum(IV): Crystal structure of [Mo{eta 2-kappa(C,S),sigma-kappa(S ')-S = C = CRC(= O)S}(= O){HB(pz)(3)}] (R = C6H4Me-4, pz = pyrazol-1-yl)

Hill AF.; White AJP.; Williams DJ.; Malget JM.

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >A thioketene complex of molybdenum(IV): Crystal structure of [Mo{eta 2-kappa(C,S),sigma-kappa(S ')-S = C = CRC(= O)S}(= O){HB(pz)(3)}] (R = C6H4Me-4, pz = pyrazol-1-yl)

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A thioketene complex of molybdenum(IV): Crystal structure of [Mo{eta 2-kappa(C,S),sigma-kappa(S ')-S = C = CRC(= O)S}(= O){HB(pz)(3)}] (R = C6H4Me-4, pz = pyrazol-1-yl)

机译：钼（IV）的硫烯酮配合物：[Mo {eta 2-k（C，S），sigma-kappa（S'）-S = C = CRC（= O）S}（= O）{HB （pz）（3）}]（R = C6H4Me-4，pz =吡唑-1-基）

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The reactions of two alkylidynemolybdenum complexes with carbon disulfide have been investigated and found to provide an unusual and structurally characterized metallacyclic thioketene complex [Mo-{eta(2)-kappa(C,S),sigma-kappa(S')-S=C=CRC(=O)S}(=O){HB-(pz)(3)}], leading to a reinterpretation of previous alkylidyne/CS2 coupling processes. [References: 12]

机译：已经研究了两种亚烷基炔钼配合物与二硫化碳的反应，发现该配合物提供了一种不寻常的结构特征化的金属环硫代乙烯酮配合物[Mo- {eta（2）-kappa（C，S），sigma-kappa（S'）-S = C = CRC（= O）S}（= O）{HB-（pz）（3）}]，从而重新解释了先前的亚烷基/ CS2偶联过程。 [参考：12]

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |1998年第3期|共3页
作者
Hill AF.; White AJP.; Williams DJ.; Malget JM.;
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正文语种 eng
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关键词
Alkylidyne; Metathesis; Carbonyl; Ligands;

机译：炔烃;复分解;羰基;配体;

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1. A thioketene complex of molybdenum(IV): Crystal structure of [Mo{eta 2-kappa(C,S),sigma-kappa(S ')-S = C = CRC(= O)S}(= O){HB(pz)(3)}] (R = C6H4Me-4, pz = pyrazol-1-yl) [J] . Hill AF., White AJP., Williams DJ., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第3期

机译：钼（IV）的硫烯酮配合物：[Mo {eta 2-k（C，S），sigma-kappa（S'）-S = C = CRC（= O）S}（= O）{HB （pz）（3）}]（R = C6H4Me-4，pz =吡唑-1-基）
2. Synthesis, electrochemistry and spectroelectrochemistry of hydrazido(2-) bridged bimetallic molybdenum species, and the X-ray crystal structure of [Mo{HB(3,5-Me(2)pz)(3})(NO)Cl](2)(mu-NHNH) in solid solution [J] . Charsley SM., Jones CJ., Neaves BD., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2002,第8期

机译：肼基（2-）桥接双金属钼物种的合成，电化学和光谱电化学，以及[Mo {HB（3,5-Me（2）pz）（3}）（NO）Cl]（2）的X射线晶体结构）（mu-NHNH）固溶体
3. METAL COMPLEXES AS HOST MOLECULES - THE X-RAY CRYSTAL STRUCTURE OF [MO(HB(3,5-ME(2)PZ)(3))(NO)(1,3-O-2-4-CH2(C6H13)C6H2)](4)CENTER-DOT-2CH(2) CL(2) [J] . Berridge TE., Hamor TA., Jones CJ., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1997,第13期

机译：金属络合物作为主分子-[MO（HB（3,5-ME（2）PZ）（3））（NO）（1,3-O-2-4-CH2（C6H13）的X射线晶体结构C6H2）]（4）CENTER-DOT-2CH（2）CL（2）
4. Nucleation of binary Cu-Se phases and electrochemical cementation mechanism on polycrystalline molybdenum thin films in Cu(II)-In(III)-Se(IV) acidic solutions [C] . O. Ramdani, B. Canava, E. Chassaing, Meeting of the Electrochemical Society . 2007

机译：二元Cu-SE相和电化学胶粘机制在Cu（II）-INSE（II） - 酸溶液中的多晶硅薄膜上的多晶钼薄膜
5. ELECTRON PARAMAGNETIC RESONANCE STUDIES OF VANADIUM(IV) AND MOLYBDENUM(V) SYSTEMS. PART I: EPR STUDIES OF UNDILUTED SINGLE CRYSTALS OF TWO VANADIUM(IV) COMPLEXES. PART II: EPR STUDIES OF FROZEN SOLUTIONS OF TWO MOLYBDENUM(V) COMPLEXES. [D] . SIMPSON, GREGORY DEWARD -1

机译：钒（IV）和钼（V）体系的电子顺磁共振研究。第一部分：两种钒（IV）络合物的未稀释单晶的EPR研究。第二部分：两种钼（V）配合物的冷冻溶液的EPR研究。
6. Spectroscopic and DFT Investigation of M{HB(35-iPr2pz)3}(SC6F5) (M = Mn Fe Co Ni Cu and Zn) Model Complexes: Periodic Trends in Metal-thiolate Bonding [O] . Serge I. Gorelsky, Lipika Basumallick, Josh Vura-Weis, -1

机译：M {HB（35-iPr2pz）3}（SC6F5）（M = MnFeCoNiCu和Zn）模型络合物的光谱和DFT研究：金属硫醇盐键合的周期性趋势
7. Reactivity of the Four-Membered Heterometallacycles CH(3,5-Me2Pz)2(CO)3WSnAr3 (Pz = Pyrazol-1-yl) with P(OR)3: Unexpected P-O/C Exchange Reactions in Phosphite [O] . -1

机译：具有P（或）3：亚磷矿中意外的P-O / C兑换反应的四元杂核基团CH（3,5-ME2PZ）2（CO）3WSNAR3（PZ =吡唑-1-基）的反应性
8. Synthesis and Crystal Structure of (Mo2FePt(mu-sigma, sigma', sigma'': eta(5)-CC5H4)2(CO)4(HB(Pz)3)2) (HB(pz)3 = Hydrotris(pyrazol-1,1-YL)Norate): A Complex Derived from a 1,1'Ferrocene Derivative with C (Triple bond) Mo(CO)2(HB(pz)3) Substituents. [R] . Davies, S. J., Hill, A. F., Pilotti, M. U., 1989

机译：（mo2Fept（μ-sigma，sigma'，sigma''：eta（5）-CC5H4）2（CO）4（HB（pz）3）2）（HB（pz）3 = Hydrotris（吡唑）的合成和晶体结构-1,1-YL）Norate）：衍生自具有C（三键）mo（CO）2（HB（pz）3）取代基的1,1'-二茂烯衍生物的络合物。

A thioketene complex of molybdenum(IV): Crystal structure of [Mo{eta 2-kappa(C,S),sigma-kappa(S ')-S = C = CRC(= O)S}(= O){HB(pz)(3)}] (R = C6H4Me-4, pz = pyrazol-1-yl)

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