Synthesis and Structure of Cadmium Complex {[Cd(adi)_(0.5)Cl(bimt)]·H2O}n

摘要

The cadmium complex {[Cd(adi)_(0.5)Cl(bimt)] H2O}n (H2adi = adipic acid, bimt = 2-((benzoimidazol-yl)methyl)-1H-tetrazole) was prepared by reaction of CdCl2·2.5H2O, bimt and H2adip in methanol/water solution and its structure was determined by single crystal X-ray diffraction analysis. The crystals are triclinic，space group P-1 with a = 8.4863(17)?，b = 8.5551(17)?，c = 11.422⑵?，α= 100.08(3)°，β= 106.33(3)°, γ= 98.37(3)°, V = 766.7(3) ?~3, Z = 2, F(000) = 434, Dc = 1.898 g/cm~3, μ= 1.623 cm~(-1), the final R = 0.0252 and wR = 0.0566. A total of 8672 reflections were collected, of which 3584 were independent (Rint = 0.0216).