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首页> 外文期刊>Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry >Photocatalytic Degradation of Acidic Blue Black 10B Using SrFe_(0.5)Co_(0.5)O_(3-δ)
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Photocatalytic Degradation of Acidic Blue Black 10B Using SrFe_(0.5)Co_(0.5)O_(3-δ)

机译:SrFe_(0.5)Co_(0.5)O_(3-δ)对酸性蓝黑10B的光催化降解

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摘要

The perovskite-type oxides SrFe_(0.5)Co_(0.5)O_(3-δ) is prepared by citrate method using strontium nitrate, iron nitrate, cobalt nitrate as raw materials. The structure of SrFe_(0.5)Co_(0.5)O_(3-δ) is characterized by X-ray diffraction, scanning electron microscopy (SEM), Brunner-Emmet-Teller (BET) measurements. The photocatalytic properties of perovskite oxides SrFe_(0.5)Co_(0.5)O_(3-δ) were evaluated by photocatalytic degradation of acid blue black 10B under the irradiation of UV. Several operational parameters effecting the photocatalytic degradation of acidic blue black 10B (AB) was studied systematically, including irradiation time, photocatalyst dose, acidic blue black 10B initial concentration and amount of H2O2 (1 %). The results showed that perovskite-type oxides SrFe_(0.5)Co_(0.5)O_(3-δ) exhibited excellent photocatalytic properties and the degradation of acidic blue black 10B followed the pseudo-first-order kinetics.
机译:以硝酸锶,硝酸铁,硝酸钴为原料,通过柠檬酸盐法制备钙钛矿型氧化物SrFe_(0.5)Co_(0.5)O_(3-δ)。 SrFe_(0.5)Co_(0.5)O_(3-δ)的结构通过X射线衍射,扫描电子显微镜(SEM),Brunner-Emmet-Teller(BET)测量来表征。钙钛矿氧化物SrFe_(0.5)Co_(0.5)O_(3-δ)的光催化性能通过在紫外线照射下酸性蓝黑10B的光催化降解来评估。系统地研究了影响酸性蓝黑10B(AB)光催化降解的几个操作参数,包括辐照时间,光催化剂剂量,酸性蓝黑10B初始浓度和H2O2(1%)的量。结果表明,钙钛矿型氧化物SrFe_(0.5)Co_(0.5)O_(3-δ)表现出优异的光催化性能,酸性蓝黑10B的降解遵循拟一级动力学。

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