Synthesis and Crystal Structure of a New Oxime-Type Zinc(II) Complex

摘要

The Zn(II) complex of an oxime has been synthesized by the reaction of 1-(4-{ [(E)-3-emoxy-2-hydroxybenzylidenelamino}phenyl)ethanone oxime and zinc(II) acetate dihydrate in the mixture of ethanol and acetonitrile. The molecule crystallizes in the triclinic system, space group P-1. Each zine(II) atom coordinates with two mono-oxime ligands in tetrahedral coordination. In the crystal structure, each molecule connects with two other molecules through two strong intermolecular N4-H4···O1 hydrogen bonds and two N2-H2···O4 intermolecuiar hydrogen bonds. Moreover, a ID supramolecular structure formed with another adjacent molecule by the two pairs of intermolecular N1-H1···O1 and N2-H2···O4 hydrogen bonds.