Effects of MgO-based expansive additive on compensating the shrinkage of cement paste under non-wet curing conditions

摘要

Expansive additives are widely used to compensate the drying shrinkage of cement-based materials to avoid cracking. However, the expansion of conventional ettringite-bearing expansive additive depends strongly on wet curing and is mainly generated at early age, and hence it may not work well in concretes without sufficient water supply or exhibit long-term shrinkage. MgO-based expansive additive, for which less water is needed for the formation of Mg(OH)_2 in comparison to ettringite, was prepared and its compensating effect on the autogenous shrinkage and late age thermal shrinkage of Portland and fly ash cement pastes at low water-to-cement ratio was investigated. The tests were conducted under sealed condition, so that the moisture exchange with the environment was prevented. Results show that, even under the non-wet curing condition, the shrinkages of cement pastes can be compensated effectively. Microstructure analysis by scanning electron microscope indicates that the macro-expansion of cement pastes is probably caused by the locally restrained expansion of MEA due to the hydration of MgO.