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Surface plasmon-enhanced terahertz spectroscopic distinguishing between isomers in powder form

机译:表面等离激元增强的太赫兹光谱可区分粉末形式的异构体

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摘要

The effect of a dielectric overlayer on terahertz transmission through a freestanding metallic array of subwavelength holes is experimentally presented. There is a remarkable resonance redshift from 0.600 to 0.498 THz at the surface plasmon (SP) metal-dielectric resonance mode with increasing film thickness. When the overlayer film is thicker than a critical thickness, the resonance frequency becomes steady at the final resonance frequency ω_f. On the basis of the dispersion relation of SPs, two kinds of glutamic acid enantiomers are distinguished by use of SP-enhanced terahertz spectra of metallic array of subwavelength holes according to the result of ω_f. The terahertz plasmonic hole array with the sensitive nature provides an approach to distinguish trace amount of powder substances, which has a promising application prospect in the fields of public security and biomedical science, such as distinguishing between isomers and identifying expensive medicines and drugs.
机译:实验性地展示了介电覆盖层对通过独立的亚波长孔金属阵列的太赫兹传输的影响。随着膜厚度的增加,在表面等离激元(SP)金属-介电共振模式下,共振的红移从0.600到0.498 THz。当覆盖膜的厚度大于临界厚度时,谐振频率稳定在最终谐振频率ω_f。根据SPs的色散关系,根据ω_f的结果,利用SP增强的亚波长孔金属阵列的太赫兹光谱来区分两种谷氨酸对映体。具有灵敏性质的太赫兹等离子体孔阵列提供了一种鉴别痕量粉状物质的方法,在公共安全和生物医学领域,如区分异构体和鉴定昂贵的药物和药物,具有广阔的应用前景。

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