Kinetics of colloidal alloy crystallization of binary mixtures of monodispersed polystyrene and/or colloidal silica spheres having different sizes and densities in microgravity using aircraft

摘要

Crystal growth rates in colloidal ahoy crystallization of binary mixtures of monodispersed polystyrene and/or silica spheres having different sizes and densities are studied in microgravity by parabolic flights of an aircraft. The crystal growth rates are obtained by time-resolved reflection spectroscopy with a continuous circulating-type stopped-flow-cell system. The growth rates of alloy crystallization increase substantially in microgravity up to about 1.7 times those in normal gravity, which is in contrast to the retarding microgravity effect on the crystallization of single-component spheres. The disappearance of the segregation effect in microgravity is the main cause for the enhancing effect. The absence of convection of the suspension and the lack of downward sedimentation of colloidal spheres are also important. [References: 36]