Regeneration of a deactivated USY alkylation catalyst using supercritical isobutane

摘要

Off-line, in situ alkylation activity recovery from a completely deactivated solid acid catalyst was examined in a continuous-flow reaction system employing supercritical isobutane. A USY zeolite catalyst was initially deactivated during the liquid phase alkylation of butene with isobutane in a single-pass reactor and then varying amounts of alkylation activity were recovered by passing supercritical isobutane over the catalyst bed at variable reactivation conditions. Temperature, pressure and regeneration time were found to play important roles in the supercritical isobutane regeneration process when applied to a completely deactivated USY zeolite alkylation catalyst. Manipulation of the variables that influence solute solubility, diffusivity, surface desorption, hydride transfer rates, and coke aging, strongly influences regeneration effectiveness. (C) 2004 Elsevier B.V. All fights reserved.