Interfacial composition, thermodynamic properties and structural parameters of water-in-oil microemulsions stabilized by 1-peetanol and mixed anionic + polyoxyethylene type nonionic surfactants

摘要

The interfacial composition (n_a~i), thermodynamic properties and structural parameters of the stable water/ (SDS + Brij-58 or Brij-78)/l-pentanol/heptane (or decane or isopropyl myristate) have been evaluated under various physicochemical environments by the dilution method. The results showed n_a~i values increase with increasing water content (ω=[water]/[surfactant]) for all the systems, whereas reverse trend was observed for (SDS/Brij-58)/heptane-derived system. The spontaneity of the transfer process of 1-pentanol from bulk oil to the interface [-ΔG_t~0] decreases with increase in ω for all the systems. The effective binding between 1-pentanol and surfactant(s) at the interface follows the order: SDS/Brij-78/IPM < SDS/Brij-58/IPM < SDS/ Brij-78/Hp(or, Dc) < SDS/Brij-58/Hp(or, Dc), which corroborates well with the degree of spontaneity of the transfer process. The Gibbs free energy change (ΔG_t~0), standard enthalpy change (AH0) and standard entropy change (ΔS_t~0) have been found to be dependent on ω, type of nonionic surfactant and its content (X_(nonionic)), oil and temperature, because of the interdependence of the partition equilibrium of Pn between bulk oil and the interface, and strong adsorption of both surfactants at the interface. Synergism in ΔAG_t~0 and (-ΔC_p~0) (standard specific heat change) is evidenced at equimolar composition of SDS and Brij-58 in both oils at all temperatures and advocates more favorable applications for the synthesis of nanoparticles and the modulation of enzyme activity. The radius of water pool (R_w) was very sensitive to the increment of water content and tuned up by the addition of Brijs, which followed the order with decreasing size: IPM < Dc < Hp.