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Dynamite Analysis by Raman Spectroscopy As a Unique Analytical Tool

机译:通过拉曼光谱法进行炸药分析作为独特的分析工具

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Apart from powerful explosives, dynamites are complex samples with an intricate analysis. These mixtures of compounds of diverse chemical nature present a challenge to the analyst, and as a result, several analytical techniques need to be applied currently for their analysis. Taking into account that presently there are almost no methods for dynamite analysis in the literature, it is crucial to develop analytical methods that could be applied for the analysis of these samples. This study introduces the use of Raman spectroscopy to analyze dynamites. Two different dynamites made up of ethylene glycol dinitrate and ammonium nitrate, among other minor components, were analyzed by Raman spectroscopy. First, confocal Raman spectroscopy allowed the identification of different components easily distinguished by eye (ammonium nitrate, ethylene glycol dinitrate, and sawdust). Then, Raman mapping was used to show the distribution of the main components throughout the dynamite mass. Finally, several minor components were identified after flocculation (nitrocellulose) or precipitation (sawdust, CaCO_3, and flour). The results obtained demonstrate the huge potential of this technique for the analysis of such a complex and tricky sample.
机译:除强大的炸药外,炸药是具有复杂分析的复杂样品。这些具有不同化学性质的化合物的混合物对分析人员提出了挑战,因此,目前需要使用几种分析技术进行分析。考虑到目前文献中几乎没有用于炸药分析的方法,因此开发可用于分析这些样品的分析方法至关重要。这项研究介绍了使用拉曼光谱分析炸药。通过拉曼光谱法分析了由亚硝酸乙二醇酯和硝酸铵以及其他次要成分组成的两种不同的炸药。首先,共焦拉曼光谱法可以识别容易用肉眼辨别的不同成分(硝酸铵,乙二醇二硝酸盐和锯末)。然后,使用拉曼映射来显示整个炸药块中主要成分的分布。最后,在絮凝(硝酸纤维素)或沉淀(木屑,CaCO_3和面粉)后,鉴定出一些次要成分。获得的结果证明了这种技术对这种复杂而棘手的样品进行分析的巨大潜力。

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