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Ionic Liquids in analytical Chemistry

机译:分析化学中的离子液体

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Room-temperature ionic liquids(RTILs),also known as liquid organic,molten,or fused salts,are a class of nonmolecular ionic solvents with low melting points.The accepted definition of an RTIL is any salt that has a melting point lower than ambient temperature(1).However,"ionic liquid"(IL)is often applied to any compound that has a melting point <100 deg C.Most common RTILs are composed of unsymmetrically substituted nitrogen-containing cations(e.g.,imidazole,pyrrolidine,pyridine)with inorganic anions(e.g.,Cl~-,PF_6~-,BF_4~-).ILs are also interesting because of their other useful and intriguing physicochemical properties.Wilkes et al.first reported ambient-temperature ILs based on the 1-alkyl-3-methylimidazolium cation in 1982(2).Since then,many ILs containing a variety of cations and anions of different sizes have been synthesized to provide specific characteristics.
机译:室温离子液体(RTIL),也称为液态有机,熔融或稠合盐,是一类具有低熔点的非分子离子溶剂。RTIL的公认定义是熔点低于环境温度的任何盐。但是,“离子液体”(IL)通常用于熔点<100℃的任何化合物。大多数常见的RTIL由不对称取代的含氮阳离子(例如咪唑,吡咯烷,吡啶)组成ILs也很有趣,因为它们还有其他有用且有趣的理化特性.Wilkes等人首先报道了基于1-烷基的环境温度ILs。 1982年,《-3-甲基咪唑鎓阳离子》(2)。从那时起,已经合成了许多包含各种阳离子和大小不同的阴离子的IL,以提供特定的特性。

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