Potassium 4,5-Bis(dinitromethyl)furoxanate: A Green Primary Explosive with a Positive Oxygen Balance

He Chunlin; Shreeve Jeanne M.

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Potassium 4,5-Bis(dinitromethyl)furoxanate: A Green Primary Explosive with a Positive Oxygen Balance

机译：4,5-双（二硝基甲基）呋喃草酸钾：具有正氧平衡的绿色初级炸药

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Potassium 4,5-bis(dinitromethyl)furoxanate was synthesized readily from cyanoacetic acid. It was characterized by IR spectroscopy, elemental analysis, NMR spectroscopy, and differential scanning calorimetry (DSC), and the structure was confirmed by X-ray single-crystal diffraction. Its positive oxygen balance, high density (2.130 gcm(-3)), sensitivity (IS=2 J, FS=5 N), and calculated heat of formation (-421.0 kJmol(-1)), combined with its calculated superior detonation performance (D=7759.0 ms(-1), P=27.3 GPa), make it a competitive replacement as a green primary explosive.

机译：由氰基乙酸容易地合成4，5-双（二硝基甲基）呋喃草酸钾。通过IR光谱，元素分析，NMR光谱和差示扫描量热法（DSC）对其进行表征，并通过X射线单晶衍射确认其结构。其正氧平衡，高密度（2.130 gcm（-3）），灵敏度（IS = 2 J，FS = 5 N）和计算出的形成热（-421.0 kJmol（-1））以及计算出的优异爆轰性能性能（D = 7759.0 ms（-1），P = 27.3 GPa），使其成为绿色初爆药的竞争替代品。

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《Angewandte Chemie》 |2016年第2期|共4页
作者
He Chunlin; Shreeve Jeanne M.;
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正文语种 eng
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energetic materials; furoxans; heterocycles; oxygen balance; primary explosives;

机译：高能材料;呋喃烷;杂环;氧平衡;主要炸药;

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1. Potassium 4,5-Bis(dinitromethyl)furoxanate: A Green Primary Explosive with a Positive Oxygen Balance [J] . He Chunlin, Shreeve Jeanne M. Angewandte Chemie . 2016,第2期

机译：4,5-双（二硝基甲基）呋喃草酸钾：具有正氧平衡的绿色初级炸药
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3. Dancing with 5-substituted monotetrazoles, oxygen-rich ions, and silver: towards primary explosives with positive oxygen balance and excellent energetic performance [J] . Sun Qi, Li Xin, Lin Qiuhan, Journal of Materials Chemistry, A. Materials for energy and sustainability . 2019,第9期

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6. Nitro- Cyano- and Methylfuroxans and Their Bis-Derivatives: From Green Primary to Melt-Cast Explosives [O] . Alexander A. Larin, Dmitry M. Bystrov, Leonid L. Fershtat, 2020

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Potassium 4,5-Bis(dinitromethyl)furoxanate: A Green Primary Explosive with a Positive Oxygen Balance

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