Regiodivergent Addition of Phenols to Allylic Oxides: Control of 1,2-and 1,4-Additions for Cyclitol Synthesis

Moschitto Matthew J.; Vaccarello David N.; Lewis Chad A.

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Regiodivergent Addition of Phenols to Allylic Oxides: Control of 1,2-and 1,4-Additions for Cyclitol Synthesis

机译：苯酚向烯丙基氧化物的区域发散性加成：控制环醇合成的1,2-和1,4-加成

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摘要

Control of 1,2- and 1,4-addition of substituted phenols to allylic oxides is achieved by intercepting palladium pi-allyl complexes. The interconversion of palladium complexes results in the total synthesis of MK7607, cyathiformine B type, streptol, and a new cyclitol.

机译：通过截取钯-π-烯丙基络合物，可以控制取代的酚向烯丙基氧化物的1,2-和1,4-加成。钯配合物的相互转化导致MK7607，Byathiformine B型，链亲和素和新的环糖醇的全合成。

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《Angewandte Chemie》 |2015年第7期|共4页
作者
Moschitto Matthew J.; Vaccarello David N.; Lewis Chad A.;
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正文语种 eng
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carbasugars; homogeneous catalysis; palladium; regiodivergence; synthetic methods;

机译：碳糖;均相催化;钯;区域发散;合成方法;
入库时间 2022-08-19 12:37:15

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专利

1. Regiodivergent Addition of Phenols to Allylic Oxides: Control of 1,2-and 1,4-Additions for Cyclitol Synthesis [J] . Moschitto Matthew J., Vaccarello David N., Lewis Chad A. Angewandte Chemie . 2015,第7期

机译：苯酚向烯丙基氧化物的区域发散性加成：控制环醇合成的1,2-和1,4-加成
2. Enantioselective synthesis of 1,2-, 1,3- and 1,4-aminoalcohols by the addition of dialkylzincs to 1,2-, 1,3- and 1,4-aminoaldehydes [J] . Lutz C., Knochel P., Lutz V. Tetrahedron . 1998,第23期

机译：通过将二烷基锌添加到1,2-，1,3-和1,4-氨基醛中来对映选择性合成1,2-，1,3-和1,4-氨基醇
3. Divergent Synthesis of CF3-Substituted Allenyl Nitriles by Ligand-Controlled Radical 1,2-and 1,4-Addition to 1,3-Enynes [J] . Wang Fei, Wang Dinghai, Zhou Yu, Angewandte Chemie . 2018,第24期

机译：通过配体控制的基团1,2-and 1,4-PATERS对CF3取代的甲烷腈的分歧合成1,3-inyn
4. Synthesis of β-(N-hydroxylamino)sulfones or thiomorpholine 1,1-dioxides via reductive 1,4-additions to vinyl or divinyl sulfones(Abstracts) [C] . Joon Hee Han, Sun Jung Lee, Jung June Lee European Symposium on Organic Chemistry . 2007

机译：通过还原1,4-加入乙烯基或二乙烯基砜（摘要）来合成β-（N-羟氨基）砜或二氧化硫1,1-二氧化氧化物（摘要）
5. The Formation of 1,2-Dioxolanes: I. By the Acid-Catalyzed Addition of H2O2 to ss,gamma-Epoxy Ketones II. By the Chromium-Catalyzed Allylic Peroxidation of a Triterpene Using O2 III. By the Metal-Catalyzed Addition of O2 to Substituted ss-Keto Esters Via an alpha-Acyl Radical. [D] . Richert, Kathleen J. 2015

机译：1,2-二氧戊环的形成：I. H2O2酸催化加成至ss，γ-环氧酮II。通过使用O2 III对三萜进行铬催化的烯丙基过氧化。通过α-酰基自由基通过金属催化将O2取代为取代的ss-Keto酯。
6. Regiodivergent Addition of Phenols to Allylic Oxides: Control of 12 and 14-Additions for Cyclitol Synthesis [O] . Matthew J. Moschitto, David N. Vaccarello, Chad A. Lewis -1

机译：苯酚向烯丙基氧化物的区域发散性加成：控制1214-加成环醇的合成
7. Regiodivergent Addition of Phenols to Allylic Oxides: Control of 1,2- and 1,4-Additions for Cyclitol Synthesis [O] . Matthew J. Moschitto, David N. Vaccarello, Chad A. Lewis 2014

机译：对烯丙基氧化物的酚醛添加酚：对甲基醇合成的1,2-和1,4-加入的控制

Regiodivergent Addition of Phenols to Allylic Oxides: Control of 1,2-and 1,4-Additions for Cyclitol Synthesis

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