Properties of Sizeable [/i]Cycloparaphenylenes as Molecular Models of Single-Wall Carbon Nanotubes Elucidated by Raman Spectroscopy: Structural and Electron-Transfer Responses under Mechanical Stress

摘要

[n]Cycloparaphenylenes behave as molecular templates of "perfectly chemically defined" single-wall carbon nanotubes. These [nJCPP molecules have electronic, mechanical, and chemical properties in size correspondence with their giant congeners. Under mechanical stress, they form charge-transfer salts, or complexes with fullerene, by one-electron concave-convex electron transfer.