Singlet oxygen (~1O_2) generation upon 1270 nm laser irradiation of ground state oxygen ('3 O _2) dissolved in organic solvents: Simultaneous and independent determination of ~1 O _2 production rate and reactivity with chemical traps

摘要

Direct photo-production of singlet oxygen, via 1270 nm laser excitation of molecular oxygen, has been the focus of recent articles. The chemical traps 1,3-diphenylisobenzofuran and rubrene are used to monitor singlet oxygen production in organic solvents through the O_2[~3Σg-] →O_2[~(1Δg)] transition. In this Letter evolution of the trap concentration is monitored continuously and we propose a new and simple method to measure singlet oxygen production rate. We derive an analytical expression for the trap disappearance rate that allows simultaneous and independent determination of the 1270 nm absorption cross section and the half quenching concentration with the chemical trap.