Spectral diffusion in solvent-filled AlPO4-5 molecular sieves: modification of amorphous phase properties by spatial restrictions

摘要

We report on persistent spectral hole-burning studies of thiazine and oxazine dyes encapsulated in an AIPO(4)-5 aluminophosphate molecular sieve. A non-photochemical hole-burning mechanism is provided by small additional solvent molecules, e.g. glassy ethanol or amorphous water. in the pore system, Hole-burning efficiency and spontaneous hole-filling are in the typical range of glassy bulk systems. However, spectral diffusion is reduced drastically in the solvent-filled molecular sieve compared to the corresponding bulk glass. Based on previous work by the Fayer group [J, Chem. Phys. 92 (1990) 4125; Chem. Phys. Lett. 168 (1990) 371] this finding is discussed as an example of spatial restrictions to the solvation shell around the dye molecules. (C) 2002 Published by Elsevier Science B.V. [References: 23]