Fluoride-ion-mediated Hydrolysis of Phosphoric Acid Esters,Amides,and Phosphorous Acid Esters Leading to Phosphorofluoridic,Phosphoramide Fluoridic,and Phosphonic Acid Monoester Salts

摘要

Fluoride-ion-promoted hydrolysis of phosphoric acid esters and amides to give phosphorofluoridic and phosphoramide fluoridic acid monoester salts takes place upon treatment with a THF solution of TBAF,whereas a similar treatment of phosphorous acid esters generates phosphonic acid monoester salts selectively without introduction of fluorine.