Synthesis and Chiral Recognition of Novel Regioselectively Substituted Amylose Derivatives

摘要

Two novel amylose derivatives la and lb bearing different substituents at 2-,3-,and 6-positions of a glucose ring have been successfully synthesized,and their abilities of enantiomer resolution in high-performance liquid chromatography (HPLC) have been evaluated.These derivatives exhibited the ability comparable or better to the commercial amylose-based column,Chiralpak AD.