From molecule to materials: Crystalline superlattices of nanoscopic CDS clusters

Levchenko T.I.; Kübel C.; Huang Y.; Corrigan J.F.

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From molecule to materials: Crystalline superlattices of nanoscopic CDS clusters

机译：从分子到材料：纳米级CDS簇的结晶超晶格

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Make way for a superlattice! A crystalline 3D superlattice of 2.3 nm molecular CdS nanoclusters was prepared from a convenient mononuclear cadmium thiophenolate precursor. HRTEM and STEM tomography show highly crystalline repetition of monodisperse frameworks (see figure). This combined with elemental and thermogravimetric analyses suggests an approximate formula [Cd_(130)S_(103)(SPh)_(54)].

机译：为超晶格让路！从方便的单核硫酚酸镉前体制备了2.3 nm分子CdS纳米簇的晶体3D超晶格。 HRTEM和STEM层析成像显示出单分散骨架的高度结晶重复性（见图）。与元素分析和热重分析相结合，提出了近似公式[Cd_（130）S_（103）（SPh）_（54）]。

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《Chemistry: A European journal》 |2011年第51期|共5页
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Levchenko T.I.; Kübel C.; Huang Y.; Corrigan J.F.;
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cadmium; chalcogens; cluster compounds; crystalline superlattices; electron tomography; solvothermal synthesis; transmission electron microscopy;

机译：镉;硫属元素;簇化合物;晶体超晶格;电子层析成像;溶剂热合成;透射电镜;

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1. From molecule to materials: Crystalline superlattices of nanoscopic CDS clusters [J] . Levchenko T.I., Kübel C., Huang Y., Chemistry: A European journal . 2011,第51期

机译：从分子到材料：纳米级CDS簇的结晶超晶格
2. Morphology Design of Crystalline and Polymer Materials from Nanoscopic to Macroscopic Scales [J] . Oaki Yuya Bulletin of the Chemical Society of Japan . 2017,第7期

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3. From Single Molecules to Nanoscopically Structured Materials: Self-Assembly of Metal Chalcogenide/Metal Oxide Nanostructures Based on the Degree of Pearson Hardness [J] . Jugal Kishore Sahoo, Muhammad Nawaz Tahir, Aswani Yella Chemistry of Materials: A Publication of the American Chemistry Society . 2011,第15期

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4. 3D Imaging of Defects in Crystalline Superlattices of CdS Clusters by Electron Tomography [C] . C. Kübel, Tetyana Levchenko, John F. Corrigan Microscopy Society of America Annual Meeting;Microanalysis Society Annual meeting;International Metallographic Society Annual meeting . 2012

机译：CdS团簇晶体超晶格缺陷的3D成像电子断层扫描
5. Structure-function relationships in crystalline and cluster-assembled materials: A study of the electronic forces in supported metal oxide catalyst precursors and heteropolyanions. [D] . Singh, David Jaikarran. 1992

机译：晶体和簇组装材料中的结构-功能关系：负载型金属氧化物催化剂前体和杂多阴离子中电子力的研究。
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8. Towards the Assembly and Characterization of Individual Molecules by Use of the Scanning Tunneling Microscope as a Nanoscopic Tool [R] . Bartels, L. 2002

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From molecule to materials: Crystalline superlattices of nanoscopic CDS clusters

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