Pd-NHC catalyzed conjugate addition versus the mizoroki-heck reaction

Gottumukkala A.L.; Devries J.G.; Minnaard A.J.

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Pd-NHC catalyzed conjugate addition versus the mizoroki-heck reaction

机译：Pd-NHC催化的共轭物加成与咪唑基-赫克反应的关系

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摘要

Ace of base: A catalytic system is presented that, solely by choice of the base, selectively switches between conjugate addition and the Mizoroki-Heck reaction of aryl halides with Michael acceptors (see scheme; R, R′=alkyl, aryl). For conjugate addition reactions, this avoids the preparation and use of organometallics.

机译：碱的原子：提出了一种催化系统，仅通过选择碱就可以在共轭加成和芳基卤化物与Michael受体的Mizoroki-Heck反应之间选择性切换（参见方案; R，R'=烷基，芳基）。对于共轭加成反应，这避免了有机金属的制备和使用。

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《Chemistry: A European journal》 |2011年第11期|共5页
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Gottumukkala A.L.; Devries J.G.; Minnaard A.J.;
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正文语种 eng
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关键词
base; carbenes.; conjugate addition; elimination; palladium;

机译：碱;卡宾;共轭加成;消除;钯;

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1. Pd-NHC catalyzed conjugate addition versus the mizoroki-heck reaction [J] . Gottumukkala A.L., Devries J.G., Minnaard A.J. Chemistry: A European journal . 2011,第11期

机译：Pd-NHC催化的共轭物加成与咪唑基-赫克反应的关系
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机译：Pd-NHC催化共轭加成与Mizoroki-Heck反应

Pd-NHC catalyzed conjugate addition versus the mizoroki-heck reaction

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