Molten salt synthesis of a SiC coating on graphite flakes for application in refractory castables

摘要

A silicon carbide coating was formed on the surface of graphite flakes by reaction of molten Si with carbon at 1100-1300 degrees C in a 95%KCI-5%NaF molten salt under Ar atmosphere. The effect of temperature and Si/graphite ratio in the initial mixture on the quality and the amount of SiC were investigated by XRD and SEM/EDS analyses. Also, the water wettability, oxidation resistance and zeta potential of un-coated and coated graphite were examined by TGA analysis and sedimentation test. The results show the amount of coating to increase in the coated flakes with increasing temperature and Si/graphite ratio. The SiC coating improves water wettability of graphite and acts as a protective layer to enhance oxidation resistance. The zeta potential of coated graphite was also increased which indicated a better dispersion in water based systems. These improvements in both the water dispersivity and oxidation resistance of SiC coated graphite would make it as promising candidate raw materials for application in C-containing refractory castables. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.