Catalytic conversion of xylose and corn stalk into furfural over carbon solid acid catalyst in gamma-valerolactone

摘要

A novel carbon solid acid catalyst was synthesized by the sulfonation of carbonaceous material which was prepared by carbonization of sucrose using 4-BDS as a sulfonating agent. TEM, N-2 adsorption-desorption, elemental analysis, XPS and FT-IR were used to characterize the catalyst. Then, the catalyst was applied for the conversion of xylose and corn stalk into furfural in GVL. The influence of the reaction time, temperature and dosage of catalyst on xylose dehydration were also investigated. The Bronsted acid catalyst exhibited high activity in the dehydration of xylose, with a high furfural yield of 78.5% at 170 degrees C in 30 min. What's more, a 60.6% furfural yield from corn stalk was achieved in 100 min at 200 degrees C. The recyclability of the sulfonated carbon catalyst was perfect, and it could be reused for 5 times without the loss of furfural yields. (C) 2016 Elsevier Ltd. All rights reserved.