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Macrokinetics of Oxidation of Ultradisperse Aluminum by Water in the liquid phase

机译:水在液相中氧化超分散铝的宏观动力学

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摘要

The processes of oxidation of electroexplosive ultradisperse powders (UDP) of aluminum by water in the range of temperatures 50-75 deg C are studied by the method of continuous recording of gas release. It is shown that the electroexplosive UDP of aluminum are capable to be actively oxidized by water with the formation of oxide-hydroxide phases and hydrogen release already upon moderate heating. At temperatures higher than 75 deg C the oxidation occurs like a degenerate thermal explosion. The macrokinetic parameters of the oxidation of aluminum UDP are determined. The data obtained can be used to assess the fire hazard of UDP in the presence of moisture and analyze the combustion of aluminum UDP in the composition of energy materials.
机译:通过连续记录气体释放的方法,研究了水在50-75摄氏度范围内用水将铝的电爆炸超分散粉末(UDP)氧化的过程。结果表明,铝的电爆炸性UDP能够被水主动氧化,形成氧化物-氢氧化物相,并且在适度加热下会释放出氢。在高于75摄氏度的温度下,氧化就像简并的热爆炸一样发生。确定了铝UDP氧化的宏观动力学参数。获得的数据可用于评估存在水分的UDP的火灾隐患,并分析铝UDP在能源材料成分中的燃烧。

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