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Liquid-crystalline polymer brushes: deformation and microphase segregation

机译:液晶聚合物刷:变形和微相偏析

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摘要

A statistical theory of the structure and thermodynamics of a planar brush ('accordion') formed by bridged polymer chains containing mesogenic segments and immersed in a solvent is developed. It is shown that deformation of an accordion can lead to the formation of a two-phase structure with coexisting liquid-crystalline (LC) and swollen microphases. Phase diagrams for accordions with different grafting densities are obtained. The influence of anisotropic interaction between mesogenic segments on the structure of phase diagrams is investigated.
机译:建立了由包含介晶链段的桥连聚合物链形成的平面刷(“手风琴”)的结构和热力学的统计理论,并浸入溶剂中。结果表明,手风琴的变形会导致液晶(LC)和微相膨胀的两相结构的形成。获得了具有不同接枝密度的手风琴的相图。研究了介晶片段之间的各向异性相互作用对相图结构的影响。

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