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首页> 外文期刊>Biomacromolecules >Characterization of Nano-Clay Reinforced Phytagel-Modified Soy Protein Concentrate Resin
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Characterization of Nano-Clay Reinforced Phytagel-Modified Soy Protein Concentrate Resin

机译:纳米粘土增强Phytagel改性大豆浓缩蛋白树脂的表征

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摘要

Phytagel and nano-clay particles were used to improve the mechanical and thermal properties and moisture resistance of soy protein concentrate (SPC) resin successfully. SPC and Phytagel were mixed together to form a cross-linked structure. The Phytagel-modified SPC resin (PH-SPC) showed improved tensile strength, modulus, moisture resistance, and thermal stability as compared to the unmodified SPC resin. The incorporation of 40% Phytagel and 20% glycerol led to an overall 340% increase in the tensile strength (over 50 MPa) and approximately 360% increase in the Young's modulus (over 710 MPa) of the SPC resin. Nano-clay was uniformly dispersed into PH-SPC resin to further improve the properties. The PH-SPC (40% Phytagel) resin modified with 7% clay nanoparticles (CPH-SPC) had a modulus of 2.1 GPa and a strength of 72.5 MPa. The dynamic mechanical properties such as storage modulus together with the glass transition temperature of the modified resins were also increased by the addition of clay nanoparticles. The moisture resistance of the CPH-SPC resin was higher as compared to both SPC and PH-SPC resins. The thermal stability of the CPH-SPC resin was seen to be higher as compared to the unmodified SPC.
机译:Phytagel和纳米粘土颗粒用于成功改善大豆浓缩蛋白(SPC)树脂的机械和热性能以及耐湿性。将SPC和Phytagel混合在一起以形成交联结构。与未改性的SPC树脂相比,Phytagel改性的SPC树脂(PH-SPC)表现出改善的拉伸强度,模量,耐湿性和热稳定性。 40%Phytagel和20%甘油的掺入导致SPC树脂的拉伸强度(超过50 MPa)总体提高了340%,杨氏模量(超过710 MPa)提高了约360%。将纳米粘土均匀分散在PH-SPC树脂中,以进一步改善性能。用7%粘土纳米颗粒(CPH-SPC)改性的PH-SPC(40%Phytagel)树脂的模量为2.1 GPa,强度为72.5 MPa。通过添加粘土纳米颗粒,还提高了动态机械性能,例如储能模量以及改性树脂的玻璃化转变温度。与SPC和PH-SPC树脂相比,CPH-SPC树脂的耐湿性更高。与未改性的SPC相比,CPH-SPC树脂的热稳定性更高。

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