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ケイ酸塩系長残光蛍光体の蛍光特性

机译:硅酸盐基长余辉荧光粉的荧光特性

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Tb~(3+)-doped and (Ce~(3+), Tb~(3+))-codoped Ca_(0.5)Sr_(0.5)Al_2SiO_7 were prepared by a solid-state reaction at 1273 K for 3 h in air and 1623 K for 6 h in a weak reductive atmosphere of 5 percent H_2-95 percent N_2 gas. The emission intensity of Tb~(3+) in the co-doped phosphor was five times higher than that of the Ce~(3+) single-doped phosphor. This is due to an energy transfer from Ce~(3+)to Tb~(3+). The co-doped phosphor showed a long-persistent phosphorescence with white color.
机译:通过在1273 K下于室温下固相反应3h,制备了掺Tb〜(3 +)和(Ce〜(3 +),Tb〜(3 +))掺杂的Ca_(0.5)Sr_(0.5)Al_2SiO_7。空气和1623 K在5%H_2-95%N_2气体的弱还原气氛中反应6小时。共掺杂磷光体中Tb〜(3+)的发射强度是Ce〜(3+)单掺杂磷光体的发射强度的五倍。这是由于能量从Ce〜(3+)传递到Tb〜(3+)。共掺杂的磷光体显示出具有白色的长持续磷光。

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