Susceptibility and inverted hysteresis loop of Prussian blue analogs with orthorhombic structure

摘要

The magnetic susceptibility of ternary metal Prussian blue analogues with orthorhombic structure is studied using Ising model. Within the frame work of effective-field theory with correlations, the roles of the mole fraction y, uniaxial magnetic anisotropy, transverse and longitudinal magnetic field are discussed in details. The temperature dependence of the magnetic susceptibility is also investigated. The interesting phenomenon of the inverted magnetic hysteresis loop has been found. The results can help to understand the experimental work of the molecule-based ferri-ferrimagnet.