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Near-Infrared Reflectance Spectroscopy as a Method for Determining Organic Carbon Concentrations in Soil

机译:近红外反射光谱法测定土壤中有机碳的含量

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摘要

Near-infrared reflectance spectroscopy (NIRS) has the potential to be a reliable method for accurately quantifying soil organic carbon (SOC). The objective of this study was to evaluate NIRS as a method for predicting SOC. Partial least squares (PLS) regression was used to predict SOC from soil reflectance values or the first derivative of the reflectance values. Two model validation techniques were evaluated: One was a full cross-validation and in the other 30 percent of the samples were removed from the calibration data set and then tested using the calibrated model. Significant relationships were observed for predicted SOC when compared to laboratory-measured SOC for all models evaluated, regardless of validation technique. The prediction models using the first derivative of the reflectance values outperformed prediction models using the reflectance values alone. In conclusion, NIRS can be used as a quick and accurate method for measuring SOC.
机译:近红外反射光谱(NIRS)有望成为准确定量土壤有机碳(SOC)的可靠方法。这项研究的目的是评估NIRS作为预测SOC的方法。使用偏最小二乘(PLS)回归从土壤反射率值或反射率值的一阶导数预测SOC。评估了两种模型验证技术:一种是完全交叉验证,另一种是从校准数据集中删除了30%的样本,然后使用校准后的模型进行测试。对于所有评估的模型,无论采用何种验证技术,与实验室测量的SOC相比,观察到的SOC预测值均存在显着关系。使用反射率值的一阶导数的预测模型优于仅使用反射率值的预测模型。总之,NIRS可以用作一种快速,准确的SOC测量方法。

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