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Extraction of D-Tartaric Acid with Alamine 336/Lix 54 Mixture

机译:Alamine 336 / Lix 54混合物萃取D-酒石酸

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摘要

Extraction equilibria in the system aqueous solution of D-tartaric acid-solution of tertiary amine in diluent at 25 deg C have been studied. The amine was Alamine 336, a long-chain tertiary amine with C_8-C_(10) alkyls in 2 : 1 ratio; the diluent was chelating extractant LIX 54, a solution of an alkyl #beta#-diketone in derosene. The experimental results were correlated using a mathematical model which takes into account chemical reactions involved in acid-amine complex formation and non-specific effects of the nonideality of the system.
机译:研究了D-酒石酸的系统水溶液-叔胺在25℃的稀释液中的萃取平衡。胺是Alamine 336,一种长链叔胺,其C 2 -C 8(10)烷基的比例为2∶1。稀释剂是螯合萃取剂LIX 54,一种烷基#beta#-二酮在二茂铁中的溶液。使用数学模型关联了实验结果,该数学模型考虑了与酸-胺络合物形成有关的化学反应和系统非理想性的非特异性作用。

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