首页> 外文期刊>Collection of Czechoslovak Chemical Communications >4,4-BIPYRIDINE-2,2',6,6'-TETRACARBOXAMIDE. SYNTHESIS AND SELF-ASSEMBLING PROPERTIES OF THE FREE BASE AND THE 1 : 1 SILVER(I) TRIFLATE COMPLEX
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4,4-BIPYRIDINE-2,2',6,6'-TETRACARBOXAMIDE. SYNTHESIS AND SELF-ASSEMBLING PROPERTIES OF THE FREE BASE AND THE 1 : 1 SILVER(I) TRIFLATE COMPLEX

机译:4,4-双吡啶-2,2',6,6'-四乙酰胺。游离碱和1:1银(I)复叶配合物的合成和自组装性能

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摘要

Self-assembly of 4,4'-bipyridine-2,2',6,6'-tetracarboxamide and its 1:1 silver(I) triflate complex was investigated by single crystal X-ray diffraction analysis. It was found that inter-molecular amide-amide hydrogen bonds control the crystal packing of the free base giving rise to infinite zig-zag tapes, whereas an octahedral coordination of the Ag(I) ion with the ligand dominates in the packing of the corresponding complex.
机译:通过单晶X射线衍射分析研究了4,4'-联吡啶-2,2',6,6'-四甲酰胺及其1:1的三氟甲磺酸银(I)配合物的自组装。发现分子间的酰胺-酰胺氢键控制游离碱的晶体堆积,产生无限的之字形带,而Ag(I)离子与配体的八面体配位在相应的堆积中占主导地位。复杂。

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