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EFFECTIVENESS OF CATALYST EXTRUDATE OF TETRALOBED CROSS SECTION UNDER CONDITIONS OF INFLUENCE OF INTERNAL DIFFUSION

机译:内扩散影响条件下四叶形截面催化剂渗出效率

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摘要

The results are summarized of mathematical modelling of the effect of internal diffusion on the rate of m-th order reaction taking place under non-isothermal conditions in the catalyst particle with tetralobed cross section. The effectiveness of the tetralobe-shaped extrudate is compared with that of cylindrical extrudate. The results obtained on the basis of mathematical modelling are confronted with the experimental data obtained on studying the dehydration reaction of cyclohexanol on cylindrical and tetralobed extrudates of gamma-alumina under the conditions of influence of internal diffusion. The experimental data are in a qualitative agreement with the theoretical ones and confirm the higher effectiveness of shaped catalyst in comparison with the cylindrical extrudate catalyst. [References: 12]
机译:结果总结了在非等温条件下,具有四叶形截面的催化剂颗粒内部扩散对m阶反应速率的影响的数学模型。将四叶形挤出物的效率与圆柱形挤出物的效率进行比较。在数学模型的基础上获得的结果与在内部扩散的影响下研究环己醇在γ-氧化铝的圆柱状和四叶状挤出物中的脱水反应所获得的实验数据相对。实验数据与理论数据在质量上吻合,并且证实了与圆柱形挤出物催化剂相比,成形催化剂的更高的有效性。 [参考:12]

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