Differential scanning calorimetry analysis of crystal structure transformation in spray-dried particles consisting of ammonium nitrate, potassium nitrate, and a polymer

摘要

Ammonium nitrate (AN) is an affordable oxidant; however, it undergoes crystal structure transformations accompanied by a change in volume at comparatively low temperatures (approx. 30, 80, and 125 ℃) and exhibits high hygroscopicity. Both these properties are particularly problematic for the industrial application of AN. In a previous study, we prepared spray-dried particles comprising three components: AN, potassium nitrate (PN) as a phase stabilizer, and a polymer (e.g., polyvinyl alcohol, carboxymethylcellulose salt, and styrene-butadiene latex), which was confirmed to provide effective moisture proofing. In the present study, the crystal transformation behavior of AN/PN/Polymer particles is investigated by observing their thermal behavior by differential scanning calorimetry. The results reveal that phase-stabilized AN can be successfully prepared by the addition of PN. In addition, an intriguing possibility was identified in that carboxymethylcellulose ammonium salt and polyvinyl alcohol, which were both added as polymer components for moisture proofing, also acted as phase stabilizers for AN crystal transformation.