BICYCLO[3.2.1]OCTENONES AS BUILDING BLOCKS IN NATURAL PRODUCT SYNTHESIS .5. FORMAL SYNTHESIS OF (+/-)-SPECIONIN

Chang MY.; Chang NC.; Chang CP.

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BICYCLO[3.2.1]OCTENONES AS BUILDING BLOCKS IN NATURAL PRODUCT SYNTHESIS .5. FORMAL SYNTHESIS OF (+/-)-SPECIONIN

机译：天然产物合成中作为构建基的双环[3.2.1]乙炔.5。正式合成（+/-）-鞘脂蛋白

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A formal synthesis (+/-)-specionin (1) is described. The key intermediate is tricyclic ketone 4. [References: 11]

机译：描述了形式合成（+/-）-specionin（1）。关键中间体是三环酮4。[参考文献：11]

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《Journal of the Chinese Chemical Society.》 |1996年第5期|共3页
作者
Chang MY.; Chang NC.; Chang CP.;
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正文语种 eng
中图分类化学;化学工业;
关键词
Iridoid sequiterpene; Specionin; (-)-specionin; Specionin; Iridoids;

机译：虹膜七烯萜;Specionin;（-）-specionin;Specionin;Iridoids;

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专利

1. BICYCLO[3.2.1]OCTENONES AS BUILDING BLOCKS IN NATURAL PRODUCT SYNTHESIS .5. FORMAL SYNTHESIS OF (+/-)-SPECIONIN [J] . Chang MY., Chang NC., Chang CP. Journal of the Chinese Chemical Society. . 1996,第5期

机译：天然产物合成中作为构建基的双环[3.2.1]乙炔.5。正式合成（+/-）-鞘脂蛋白
2. Synthesis and agrochemical screening of a library of natural product-like bicyclo(2,2,2)octenones. [J] . Smith SC, James DR, Abelman MM, Combinatorial chemistry & high throughput screening . 2005,第7期

机译：天然产物样双环（2,2,2）辛烯酮文库的合成和农用化学筛选。
3. Synthesis and agrochemical screening of a library of natural product-like bicyclo[2,2,2]octenones [J] . Stephen C. Smith Donald R. James Matthew M. Abelman Graham J. Sexton Combinatorial Chemistry & High Throughput Screening . 2005,第7期

机译：天然产物样双环[2,2,2]辛烯酮文库的合成与农药化学筛选
4. Biotransformations in Natural Product Synthesis -Efficient Access to Chiral Building Blocks [C] . Diana Sandkuhl, Thomas Fischer, Jorg Pietruszka European Symposium on Organic Chemistry . 2009

机译：自然产品综合的生物转化 - 对手性建筑块的效率接近
5. Part I. One-pot synthesis of secondary alcohols and one-pot asymmetric synthesis of secondary propargylic alcohols. Part II. Redox isomerization of secondary propargylic alcohols to enones. Part III. Synthesis study towards C9-C14 fragment of (+)-discodermolide. Part IV. Asymmetric synthesis of anti, anti-stereotriad building blocks for polypropionate natural products [D] . Xie, Qiuzhe 2007

机译：第一部分：仲醇的一锅法合成和仲炔丙醇的一锅法不对称合成。第二部分仲炔丙醇的氧化还原异构化为烯酮。第三部分（+）-discodermolide C9-C14片段的合成研究。第四部分聚丙烯酸酯天然产物的抗，抗立体三环构建基的不对称合成
6. Synthesis of most polyene natural product motifs using just twelve building blocks and one coupling reaction [O] . Eric M. Woerly, Jahnabi Roy, Martin D. Burke -1

机译：仅用十二种结构单元和一个偶联反应即可合成大多数多烯天然产物基序
7. Chiral synthesis of polyketide-derived natural products. 44. Large Laboratory scale Synthesis of (2S,3S)-2-(4-Methoxybenzyloxy)-3,4-O-(3-pentylidene)-1,3,4-butantriol, a Versatile Chiral Building Block in Natural Product Synthesis. [O] . Kiyoshi HORITA, Youji SAKURAI, Shun-ichiro HACHIYA, 1994

机译：细胞合成聚酮衍生的天然产物。 44.大型实验室规模合成（2S，3S）-2-（4-甲氧基苄氧基）-3,4-O-（3-四苯基）-1,3,4-丁烷醇，天然产物合成的多功能手性构建块。

BICYCLO[3.2.1]OCTENONES AS BUILDING BLOCKS IN NATURAL PRODUCT SYNTHESIS .5. FORMAL SYNTHESIS OF (+/-)-SPECIONIN

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