Oligomeric isoflavonoids. Part 4. Synthesis of the daljanelin class of isoflavonoid-neoflavonoid dimers

摘要

A protocol of introducing an electrophilic C_1 fragment to a pterocarpan nucleus, followed by anionic coupling of a C_6-C_2 benzofuranoid precursor and late introduction of the final C_6 fragment, permitted the syntheses of daljanelins B 3 and D 5. The feasibility of introducing the same electrophilic C_1 fragment to C-2 of the pterocarpan moiety to obtain a precursor to daljanelin A 2 was also demonstrated.