A versatile and convenient method for the synthesis of substituted benzo[a]carbazoles and pyrido[2,3-a]carbazoles

de Koning CB.; Rousseau AL.; Michael JP.

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A versatile and convenient method for the synthesis of substituted benzo[a]carbazoles and pyrido[2,3-a]carbazoles

机译：一种通用且方便的合成取代苯并[a]咔唑和吡啶并[2,3-a]咔唑的方法

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Treatment of 2-(o-tolyl)- or 2-(3-methyl-2-pyridyl)-substituted indole-3-carbaldehydes with potassium tert-butoxide in DMF at 70-80 degrees C with simultaneous irradiation from a 400 W high-pressure mercury lamp afforded benzo[a]carbazoles and pyrido[2,3-a]carbazoles respectively in good yields. [References: 64]

机译：用叔丁醇钾在DMF中在70-80摄氏度下用400 W高功率同时照射处理2-（邻甲苯基）-或2-（3-甲基-2-吡啶基）-取代的吲哚-3-甲醛高压汞灯分别以良好的产率提供了苯并[a]咔唑和吡啶并[2,3-a]咔唑。 [参考：64]

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《Journal of the Chemical Society, Perkin Transactions 1 》 |2000年第0期| 共9页
作者
de Koning CB.; Rousseau AL.; Michael JP.;
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正文语种 eng
中图分类有机化学 ;
关键词
Diels-alder reactions; Cross-coupling reactions; Palladium(0)-catalyzed heteroarylation; lt; agt; annulated carbazoles; Indole-derivatives; Antitumor-activity; Palladium; Alkaloids; Access; 3-vinylindoles;

机译：Diels-alder反应;交叉偶联反应;钯（0）催化的杂芳基化;环化咔唑;吲哚衍生物;抗肿瘤活性;钯;生物碱;接触;3-乙烯基吲哚;

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1. A versatile and convenient method for the synthesis of substituted benzo[a]carbazoles and pyrido[2,3-a]carbazoles [J] . Charles B.de Koning, Joseph P.Michael, Amanda L.Rousseau Journal of the Chemical Society, Perkin Transactions 1 . 2000 ,第11期

机译：一种通用且方便的合成取代苯并[a]咔唑和吡啶并[2,3-a]咔唑的方法
2. A CONVENIENT ROUTE FOR THE SYNTHESIS OF CIS -1-SUBSTITUTED l,2,3,4,4a,5,l 1,1 la-OCTAHYDRO-6H-PYRIDO[3,2-b]CARBAZOLES AND 4-SUBSTITUTED 1,2,3,4,4a,5,6,llc-OCTAHYDRO-7H-PYRIDO[2,3-c] CARBAZOLES AS POTENT DOPAMINE AGONISTS. [J] . Keshav K.Awasthi, Ruchika Chakrabarty, Anil K.Saxena Medicinal chemistry research: an international journal for rapid communications on design and mechanisms of action of biologically active agents . 2004 ,第8a9期

机译：合成CIS -1-取代的l，2,3,4,4a，5，l 1,1 la-OCTAHYDRO-6H-PYRIDO [3,2-b]咔唑和4-取代的1,2的便捷路线，3,4,4a，5,6，llc-OCTAHYDRO-7H-PYRIDO [2,3-c]咔唑作为强力多巴胺激动剂。
3. SYNTHESIS OF 11H-PYRIDO[2,3-A]CARBAZOLES AND 6H-PYRIDO[3,2-B]CARBAZOLES FROM 8-METHOXY BROMOQUINOLINES [J] . Trecourt F., Mongin F., Queguiner G., Tetrahedron . 1995 ,第43期

机译：由8-羟基溴代喹啉合成11H-吡啶并[2,3-A]咔唑和6H-吡啶并[3,2-B]咔唑
4. Synthesis and Characterization of Novel Blue-Light-Emitting Fluorene-Carbazole Copolymers with Boryl Substitutions [C] . Yinq-Hsiao Chen, Yu-Ying Lin, Yung-Chung Chen, IDW '10;International display workshops . 2011

机译：具有硼取代基的新型发蓝光芴-咔唑共聚物的合成与表征
5. Synthesis of benzo[a]carbazoles and indolo[2,3-a]carbazoles using a combined directed ortho metalation-cross coupling strategy. [D] . Cai, Xiongwei. 2006

机译：苯并[a]咔唑和吲哚[2,3-a]咔唑的合成使用定向定向金属交叉偶联策略。
6. From Quinoxaline Pyrido23-bpyrazine and Pyrido34-bpyrazine to Pyrazino-Fused Carbazoles and Carbolines [O] . Frédéric Lassagne, Timothy Langlais, Elsa Caytan, 2018

机译：从喹喔啉吡咯并23-b吡嗪和吡咯并34-b吡嗪到吡嗪并氟并咔唑和咔啉
7. Design and Synthesis of a Fluoroindolocarbazole Series as Selective Topoisomerase-I Active Agents. Discovery of Water Soluble 3, 9-Difluoro-12, 13-dihydro-13-6-amino-b-D-glucopyranosyl-5H, 13H-benzo-b-thienyl 2, 3-a pyrrolo 3, 4-c carbazole-5, 7(6 [O] . -1

机译：氟吲哚咔唑系列作为选择性拓扑异构酶-I活性剂的设计与合成。发现水溶性3,9-二氟-12,13-二氢-13- 6-氨基-BD-吡喃葡萄糖基 -5H，13H-苯并-B - 噻吩基2,3-A Pyrrolo 3， 4-C咔唑-5,7（6
8. Fluorescence Quenching of Carbazole by Pyridine and Substituted Pyridines. Radiationless Processes in the Carbazole-Amine Hydrogen Bonded Complex. [R] . Martin, M. M., Ware, W. R. 1978

机译：吡啶和取代吡啶对咔唑的荧光猝灭。咔唑 - 胺氢键复合物中的无辐射过程。

A versatile and convenient method for the synthesis of substituted benzo[a]carbazoles and pyrido[2,3-a]carbazoles

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