Electrophoretic deposition of titania-carbon nanotubes nanocomposite coatings in different alcohols

摘要

The suspensions of titania nanoparticles in different alcohols (methanol, ethanol and butanol) were prepared using triethanolamine (TEA) as a dispersant. The optimum concentration of TEA was 16.67, 8 and 0.33 mL/L in methanol, ethanol and butanol, respectively. Two component suspensions of titania (20 g/L) and carbon nanotubes (CNTs) (0.1,0.2,0.5 and 1 g/L) were prepared in different alcohols without and with optimum concentration of TEA. The finer and positively charged titania nanoparticles were heterocoagulatcd on the surface of coarser and negatively charged CNTs and generated the titania-CNT composite particles with the net positive charge. In the presence of TEA, titania nanoparticles completely covered CNTs surface due to their higher positive surface charge. At same CNT concentration, the deposition rate was faster for suspensions with TEA additive due to the faster mobility of the composite particles. The photocatalysis efficiency of coatings for methylene blue degradation increased as CNTs were incorporated in their microstructure.