The first chiral 2-D molecular triangular grid

摘要

The two-dimensional coordination polymer, [Cu(PPh_3)(N, N-(2-pyridyl)(4-pyridylmethyl)amine)_(1.5)]·0.5CHCl_3·ClO_4 1, with a large chiral triangular cavity and blue fluorescent emission, was synthesized by a solvolthermal reaction between [Cu(MeCN)_2(PPh_3)_2]ClO_4 and N, N-(2-pyridyl)(4-pyridylmethyl)amine.