Combustion of the 'Ti-TiO_2' and 'Ti-Al' powdery mixtures in air

摘要

The combustion synthesis in "Ti-TiO_2" and "Ti-Al" powdery mixtures in air under atmospheric pressure has been studied. The results of X-ray diffraction analysis showed TiN and A1N as prevalent phases in the combustion products. Hence, the deep interaction with atmospheric nitrogen during metals combustion in air occurs. The mechanism of TiN and A1N formation instead of thermodynamically stable TiO_2 and Al_2O_3 formation by burning in air is proposed on the basis of XRD and SEM data.