Organo-scandium and -yttrium complexes supported by a salicylaldiminato ligand

摘要

Reaction of a salicylaldiminato ligand with M(CH_2-SiMe_2Ph_3)(THF)_2 (M = Sc, Y) leads to diastereoselective formation of highly thermally stable L_2MR complexes whose reactivity with dihydrogen to form Group3 metal hydrides is described.