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首页> 外文期刊>Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry >Preparation, structures and reactions of isomeric [Co(cyclen)(O_2C_2O_2)]~+ and [Co(cyclen)(O_2CCH_2CO_2)]~+ complexes (cyclen = 1,4,7,10-tetraazacyclododecane)
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Preparation, structures and reactions of isomeric [Co(cyclen)(O_2C_2O_2)]~+ and [Co(cyclen)(O_2CCH_2CO_2)]~+ complexes (cyclen = 1,4,7,10-tetraazacyclododecane)

机译:[Co(cycln)(O_2C_2O_2)]〜+和[Co(cycln)(O_2CCH_2CO_2)]〜+异构体(周期数= 1,4,7,10-四氮杂环十二烷)的制备,结构和反应

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摘要

The syn, anti and syn, syn forms of the complexes [Co(cyclen)(O_2C_2O_2)]ClO_4 1 and 2 respectively and [Co(cyclen)(O_2CCH_2CO_2)][ClO_4](centre dot)H_2O 3 and 4 respectively (cyclen = 1,4,7,10-tetraazacyclododecane) have been prepared and their single crystal structures determined.
机译:分别[Co(cyclen)(O_2C_2O_2)] ClO_4 1和2和[Co(cyclen)(O_2CCH_2CO_2)] [ClO_4](中心点)H_2O 3和4(周期制备了1,4,7,10-四氮杂环十二烷)并确定了其单晶结构。

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