Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions

Yan Xu; Dun-Ru Zhu; Zi-Jian Guo; Yu-Jun Shi; Kou-Lin Zhang; Xiao-Zeng You

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Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions

机译：阳离子诱导的第一个钼-钒-十六金属混合主壳簇阴离子的组装

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Two novel hexadecametal-oxygen cluster compounds, {Ni(NH_2)_2(C_2H_4)_2NH_2}_3[PMo_5~(VI)Mo_3~VV_8~(IV)O_(44)].[(NH_2)_2(C2H_4)_2NH].H_2O 1 and {Co[(NH_2)_2(C2H_4)_2NH_2]_2}Na-[PMo_6~(VI)Mo_2~VV_8~(IV)O_(44)].8H_2O 2 are synthesized by a bydrothermal method, and characterized by X-ray crystallography, showing that the anion of 1 has a novel terta-capping mode, and that the first hexadecametaloxygen host sheel is observed in 2

机译：两个新颖的十六金属-氧簇化合物{Ni（NH_2）_2（C_2H_4）_2NH_2} _3 [PMo_5〜（VI）Mo_3〜VV_8〜（IV）O_（44）]。[（NH_2）_2（C2H_4）_2NH]。 H_2O 1和{Co [（NH_2）_2（C2H_4）_2NH_2] _2} Na- [PMo_6〜（VI）Mo_2〜VV_8〜（IV）O_（44）]。8H_2O 2的合成方法是热解法，其特征在于X射线晶体学分析，显示1的阴离子具有新颖的叔封端模式，并且在2中观察到第一个十六金属氧烷

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《Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry》 |2001年第6期|共2页
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Yan Xu; Dun-Ru Zhu; Zi-Jian Guo; Yu-Jun Shi; Kou-Lin Zhang; Xiao-Zeng You;
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1. Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions [J] . Yan Xu, Dun-Ru Zhu, Zi-Jian Guo, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2001,第6期

机译：阳离子诱导的第一个钼-钒-十六金属混合主壳簇阴离子的组装
2. The first discrete mixed-valence hexadecavanadate host shell cluster anions: hydrothermal synthesis,structure an characterization of[V_(16)O_(38)(Cl)]~(8-) [J] . Yanhui Chen, Xiaojun Gu, Jun peng, Inorganic Chemistry Communications . 2004,第5期

机译：第一个离散的混合价十六烷钒酸酯主体壳簇阴离子：水热合成，结构表征[V_（16）O_（38）（Cl）]〜（8-）
3. Hydrated anion glued capsular and non-capsular assembly of a tripodal host: Solid state recognition of bromide-water [Br-5-(H2O)(6)](5-) and iodide-water [I-2-(H2O)(4)](2-) clusters in cationic tripodal receptor [J] . Hoque Md. Najbul, Das Gopal CrystEngComm . 2014,第21期

机译：三脚架主体的水合阴离子胶胶囊和非胶囊组件：溴化物-水[Br-5-（H2O）（6）]（5-）和碘化物-水[I-2-（H2O）（ 4）]（2-）簇在阳离子三脚架受体中
4. Templated Assembly of Metal-Anion Arrays within Layered Hosts; Synthesis and Characterization of New Transition-Metal Oxyhalide Perovskites [C] . Gabriel Caruntu, Liliana Viciu, Leonard Spinu, Symposium on Perovskite Materials, Apr 1-5, 2002, San Francisco, California . 2002

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5. Self-assembly and host-guest chemistry of cationic titanium and mixed, neutral-charged, platinum(II) and palladium(II) macrocyclic tetranuclear complexes. [D] . Whiteford, Jeffery Alan. 1997

机译：阳离子钛以及混合的，中性电荷的铂（II）和钯（II）大环四核配合物的自组装和客体化学。
6. Anion Cluster: Assembly of Dihydrogen Phosphates for the Formation of a Cyclic Anion Octamer [O] . Md. Alamgir Hossain, Muhammet Işıklan, Avijit Pramanik, -1

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7. Open Shells in Endohedral Clusters: Structure and Bonding in the Fe2@Ge164 Anion and Comparison to Isostructural Co2@Ge164 [O] . -1

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8. Probing Metal Cluster and Metal Oxide Cluster Interactions with Organo- Sulfur and Organo-Phosphorous Molecules using Mass Spectrometry and Anion PES [R] . Jarrold, C. C. 2002

机译：利用质谱和阴离子pEs探测金属团簇和金属氧化物团簇与有机硫和有机磷分子的相互作用

Cation-induced assembly of the first mixed molybdenum-vanadium hexadecametal host shell cluster anions

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