Turning dihydrogen gas into a strong acid. Formation and reactions of the very acidic ruthenium dihydrogen complexes trans-[Ru(H-2)-(CNH){PPh2(CH2)(n)PPh2}(2)][O3SCF3](2) (n = 2 or 3)

Fong TP.; Morris RH.; Mezzetti A.; Rocchini E.; Rigo P.; Lough AJ.

首页> 外文期刊>Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry >Turning dihydrogen gas into a strong acid. Formation and reactions of the very acidic ruthenium dihydrogen complexes trans-[Ru(H-2)-(CNH){PPh2(CH2)(n)PPh2}(2)][O3SCF3](2) (n = 2 or 3)

【24h】

Turning dihydrogen gas into a strong acid. Formation and reactions of the very acidic ruthenium dihydrogen complexes trans-[Ru(H-2)-(CNH){PPh2(CH2)(n)PPh2}(2)][O3SCF3](2) (n = 2 or 3)

机译：将氢气转化为强酸。酸性很强的钌二氢配合物的形成和反应-[Ru（H-2）-（CNH）{PPh2（CH2）（n）PPh2}（2）] [O3SCF3]（2）（n = 2或3）

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

New, very acidic ruthenium dihydrogen complexes containing the hydrogen isocyanide ligand have been synthesised; when formed under 1 atm H-2 they have been shown to spontaneously eliminate trifluoromethylsulfonic acid. [References: 16]

机译：合成了新的酸性很强的含有异氰酸氢配体的钌二氢配合物;当在1 atm H-2下形成时，它们被证明可自发消除三氟甲基磺酸。 [参考：16]

著录项

来源
《Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry》 |1998年第13期|共3页
作者
Fong TP.; Morris RH.; Mezzetti A.; Rocchini E.; Rigo P.; Lough AJ.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Ligand; Heterolysis; Reactivity;

机译：配体;裂解;反应性;

相似文献

外文文献
专利

1. Turning dihydrogen gas into a strong acid. Formation and reactions of the very acidic ruthenium dihydrogen complexes trans-[Ru(H-2)-(CNH){PPh2(CH2)(n)PPh2}(2)][O3SCF3](2) (n = 2 or 3) [J] . Fong TP., Morris RH., Mezzetti A., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1998,第13期

机译：将氢气转化为强酸。酸性很强的钌二氢配合物的形成和反应-[Ru（H-2）-（CNH）{PPh2（CH2）（n）PPh2}（2）] [O3SCF3]（2）（n = 2或3）
2. Protonation reactions of trans-M(H)(SPh)(dppe)(2) (M = Ru, Os) to give thiol and dihydrogen complexes. X-ray crystal structure determination of trans-Ru(H)(SPh)(dppe)(2) and trans-[Os(H)(O-2)(dppe)(2)](O3SCF3) [J] . Bartucz TY., Lough AJ., Maltby PA., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第7期

机译：反式-M（H）（SPh）（dppe）（2）（M = Ru，Os）的质子化反应，得到硫醇和二氢配合物。反式Ru（H）（SPh）（dppe）（2）和反式[Os（H）（O-2）（dppe）（2）]（O3SCF3）的X射线晶体结构测定
3. Synthesis and reactions of the cationic seven-coordinate complexes, [MoI(CO)(3)(NCR){Ph2P(CH2)(n)PPh2}][BF4] (R = Me, n = 1, 2 and 3; R = Et, n=1). Crystal structures of [MoI2(CO)(2)(PPh3){Ph2P(CH2)PPh2}], [MoI(CO)(2){Ph2P(CH2)PPh2}(2)][BF4]center do [J] . Baker PK., Drew MGB., Moore DS. Journal of Organometallic Chemistry . 2002,第1a2期

机译：阳离子七配位化合物[MoI（CO）（3）（NCR）{Ph2P（CH2）（n）PPh2}] [BF4]的合成和反应（R = Me，n = 1，2和3; R = Et，n = 1）。 [MoI2（CO）（2）（PPh3）{Ph2P（CH2）PPh2}]，[MoI（CO）（2）{Ph2P（CH2）PPh2}（2）] [BF4]中心的晶体结构
4. Mechanistic Investigation on Dihydrogen Activation Reactions by Ruthenium(II) Complexes Bearing Hydroxygermanethiolates [C] . Tsuyoshi Matsumoto, Yukiko Nakaya, Kazuyuki Tatsumi Symposium on Organometallic Chemistry . 2004

机译：钌（II）含羟基硫酸甲磺酸盐的钌（II）复合物的含二氢活化反应的机械研究
5. I. Stereochemistry of cyclopropane formation involving group (IV) organometallic complexes. II. Slower stoichiometric and faster catalytic reduction of aldehydes by the PPh(3) substituted hydroxycyclopentadienyl ruthenium hydride [2,5-Ph(2)-3,4-Tol(2)(eta(5)-C(4)COH)]Ru(CO)(PPh(3))H: A highly chemoselective catalyst for hydrogenation of aldehydes over ketones. [D] . Strotman, Neil Adham. 2005

机译：I.涉及（IV）族有机金属配合物的环丙烷形成的立体化学。二。由PPh（3）取代的羟基环戊二烯基氢化钌[2,5-Ph（2）-3,4-Tol（2）（eta（5）-C（4）COH）] Ru的化学计量较慢和较快的醛催化还原（CO）（PPh（3））H：一种高度化学选择性的催化剂，用于醛在酮上的氢化。
6. Scope and Mechanistic Investigations on the Solvent-Controlled Regio- and Stereoselective Formation of Enol Esters from the Ruthenium-Catalyzed Coupling Reaction of Terminal Alkynes and Carboxylic Acids [O] . Chae S. Yi, Ruili Gao -1

机译：从终端炔烃和羧酸的钌催化偶联反应烯醇酯的溶剂控制的区域选择性和立体选择性合成范围和机理的调查
7. Reaction of the Ruthenium(II) Indenyl Complex Ru(h5-C9H7){k3(P, C, C)-PPh2(CH2CHdCH2)} (PPh3)PF6 with Terminal Alkynes. Mechanisms of 1-Alkyne to h1-Vinylidene Transformation and Kinetic Detection of Hemilability of the Allylphosphine Ligand [O] . -1

机译：钌（II）茚基复合物Ru（H5-C9H7）的反应（H5-C9H7）{K3（P，C，C）-PPH2（CH2CHDCH2）}（PPH3）PF6与末端炔烃。 1-炔氧基对H1-偏二苯基转化的机制和烯丙基膦配体的杆状动性的动力学检测
8. Reaction Chemistry of Transition Metal Diphenylphosphorus Complexes with Organoaluminum Compounds. The Synthesis, Characterization and Crystal and Molecular Structure of Cr(CO)5(PPh2(CH2)4OA1(CH2SiMe3)2), an Example of THF Cleavage. [R] . Tessier-Youngs, C., Youngs, W. J., Beachley, O. T., 1983

机译：过渡金属二苯基磷配合物与有机铝化合物的反应化学。 Cr（CO）5（pph2（CH2）4Oa1（CH2sime3）2）的合成，表征和晶体和分子结构，THF裂解的实施例。

Turning dihydrogen gas into a strong acid. Formation and reactions of the very acidic ruthenium dihydrogen complexes trans-[Ru(H-2)-(CNH){PPh2(CH2)(n)PPh2}(2)][O3SCF3](2) (n = 2 or 3)

摘要

著录项

相似文献

相关主题

期刊订阅