Decarboxylation reactions of alkyne-carboxylic acids as a route to multiply bonded [Re_2]~(n+) #mu#-*alkyne and #mu#-carbyne complexes

Jitendra K. Bera; Phillip E. Fanwick; Richard A. Walton

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Decarboxylation reactions of alkyne-carboxylic acids as a route to multiply bonded [Re_2]~(n+) #mu#-*alkyne and #mu#-carbyne complexes

机译：炔烃-羧酸的脱羧反应作为多重键合的[Re_2]〜（n +）#mu＃-*炔烃和＃mu＃-carbyne配合物的途径

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Multiply bonded organometallic complexes Re_2(#mu#-CI)(#mu#-#eta#~2-HCCH)CI_4(#mu#-dppm)_2 (2) and Re_2(#mu#-CI)(#mu#-CCH_2CH_3)CI_4(#mu#-dppm)_2 (3).

机译：多重键合的有机金属络合物Re_2（＃mu＃-CI）（＃mu＃-＃eta＃〜2-HCCH）CI_4（＃mu＃-dppm）_2（2）和Re_2（＃mu＃-CI）（＃mu＃ -CCH_2CH_3）CI_4（＃mu＃-dppm）_2（3）。

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《Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry》 |2001年第2期|共12页
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Jitendra K. Bera; Phillip E. Fanwick; Richard A. Walton;
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1. Decarboxylation reactions of alkyne-carboxylic acids as a route to multiply bonded [Re_2]~(n+) #mu#-*alkyne and #mu#-carbyne complexes [J] . Jitendra K. Bera, Phillip E. Fanwick, Richard A. Walton Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2001,第2期

机译：炔烃-羧酸的脱羧反应作为多重键合的[Re_2]〜（n +）#mu＃-*炔烃和＃mu＃-carbyne配合物的途径
2. Mixed Chloride/Phosphine Complexes of the Dirhenium Core. 10. Redox Reactions of an Ede-Sharing Dirhenium(III) Non-metal-Metal-Bonded Complex, Re_2(#mu#-Cl)_2(PMe_3)_4 [J] . F. Albert Cotton, Evgeny V. Dikarev, Marina A. Petrukhina Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第26期

机译：ir核的混合氯化物/膦配合物。 10. Ede-共享Dirhenium（III）非金属键合复合物Re_2（＃mu＃-Cl）_2（PMe_3）_4的氧化还原反应。
3. Mixed Chloride/Phosphine Complexes of the Dirhenium Core. 10. Redox Reactions of an Ede-Sharing Dirhenium(III) Non-metal-Metal-Bonded Complex, Re_2(#mu#-Cl)_2(PMe_3)_4 [J] . F. Albert Cotton, Evgeny V. Dikarev, Marina A. Petrukhina Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第26期

机译：ir核的混合氯化物/膦配合物。 10. Ede-共享Dirhenium（III）非金属键合复合物Re_2（＃mu＃-Cl）_2（PMe_3）_4的氧化还原反应。
4. MECHANISTIC INVESTIGATION INTO THE DECARBOXYLATION OF AROMATIC CARBOXYLIC ACIDS AND THEIR ROLE IN RETROGRESSIVE REACTIONS [C] . Phillip F. Britt, A. C. Buchanan III National Meeting Exhibition . 2012

机译：芳族羧酸脱羧及其在倒退反应中的作用的机械研究及其作用
5. Transition metal-catalyzed tandem carbon-oxygen and carbon-carbon bond forming reactions of alkynes in (1) the addition-cyclization of carboxylic acids with 1,6-diynes and in (2) the total synthesis of frondosin B. [D] . Goble, Stephen D. 2006

机译：炔烃的过渡金属催化串联碳-氧和碳-碳键形成反应在（1）羧酸与1,6-二炔的加成环化中和（2）frondosin B的总合成中。
6. Co-complexes Derived from Alkene Insertion to Alkyne-dicobaltpentacarbonyl complexes: Insight into the Regioselectivity of Pauson-Khand Reactions of Cyclopropenes [O] . Mahesh K. Pallerla, Glenn P. A. Yap, Joseph M. Fox -1

机译：从烯烃插入到炔-二钴五羰基配合物的共配合物：环丙烯的Pauson-Khand反应的区域选择性的见解
7. Alkyne Exchange Reactions of Silylalkyne Complexes of Tantalum: Mechanistic Investigation and Its Application in the Preparation of New Tantalum Complexes Having Functional Alkynes (PhCtCR (R = COOMe, CONMe2)) [O] . -1

机译：纳利甘露糖糖综合体的炔烃交换反应：机械调查及其在制备具有功能性alkynes的新钽络合物中的应用（phctcr（r = coome，conme2））
8. Formation of Sixteen-Electron Alkyne Complexes by Reaction of Halogeno(Tricarbonyl) (eta5-Cyclopentadienyl)-Molybdenum and -Tungsten Complexes with Alkynes; Crystal and Molecular Structure of (WCl (CF3C2CF3) sub 2-(eta5-C5H5)). [R] . Davidson, J. L., Green, M., Gordon, F., 1975

机译：通过卤素（三羰基）（η5-环戊二烯基） - 钼和钨配合物与炔烃的反应形成16-电子炔烃配合物; （WCl（CF3C2CF3）sub 2-（eta5-C5H5））的晶体和分子结构。

Decarboxylation reactions of alkyne-carboxylic acids as a route to multiply bonded [Re_2]~(n+) #mu#-*alkyne and #mu#-carbyne complexes

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