Structural and spectroscopic studies on three-and two-co-ordinate copper(I) halide tribenzylphosphine complexes

摘要

Three-co-ordinate, monomeric 1:2 complexes of tribenzylphosphine (PBz_3) with copper(I) halides, [Cu(Pbz_3)X] (X=Cl, Br, or I), have been synthesized and characterized by single crystal structure determinations, solid state ~931)PCPMAS NMR spectroscopy and low frequency vibrational spectroscopy.