An unprecedented six-fold anion-type chiral diamondoid-like eight-coordinate Cd(II) coordination polymer with a second-order nonlinear optical effect

摘要

The reaction of Cd(OH)(2) with 3,3'-azodibenzoic acid affords an unprecedented anionic chiral diamondoid network, bis(3,3'-azodibenzoate)cadmium.(H2NMe2)(NH4) which contains eight-coordinate cadmium and displays strong SHG response and enantioselectivity for organic amines. [References: 33]