Alkali-metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand

Garth R. Giesbrecht; Andreas Gebauer; Alex Shafir; John Arnold

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Alkali-metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand

机译：三氮杂双环壬烷官能化的四甲基环戊二烯基配体的碱金属配合物

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Reaction of (1, 4-diisopropyl-1, 4, 7-triazacyclononane)Li with C_5Me_4HSiMe_2Cl yields the new donor-functionalized ligand, [C_5Me_4SiMe_2(tacn)]H; the alkali-metal salts [C_5Me_4SiMe_2(tacn)]M (M = Li, Na, K) are obtained upon reaction with BuLi, NaN(SiMe_3)_2 or KN(SiMe_3)_2.

机译：（1,4-二异丙基-1,4,7-三氮杂环壬烷）Li与C_5Me_4HSiMe_2Cl的反应产生新的供体官能化的配体[C_5Me_4SiMe_2（tacn）] H;碱金属盐[C_5Me_4SiMe_2（tacn）] M（M = Li，Na，K）与BuLi，NaN（SiMe_3）_2或KN（SiMe_3）_2反应后得到。

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《Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry》 |2000年第22期|共3页
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Garth R. Giesbrecht; Andreas Gebauer; Alex Shafir; John Arnold;
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1. Alkali-metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand [J] . Garth R. Giesbrecht, Andreas Gebauer, Alex Shafir, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2000,第22期

机译：三氮杂双环壬烷官能化的四甲基环戊二烯基配体的碱金属配合物
2. Divalent lanthanide metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand: X-ray crystal structures of [C5Me4SiMe2(Pr-i(2)-tacn)]LnI (Ln = Sm, Yb; tacn = 1,4-diisopropyl-1,4,7-triazacyclononane) [J] . Giesbrecht GR., Cui CM., Shafir A., Organometallics . 2002,第18期

机译：三氮杂双环壬烷官能化的四甲基环戊二烯基配体的二价镧系金属配合物：[C5Me4SiMe2（Pr-i（2）-tacn）] LnI的X射线晶体结构（Ln = Sm，Yb; tacn = 1,4-二异丙基-1,4 ，7-三氮杂环壬烷）
3. Alkali-Metal Complexes of a Tetramethylcyclopentadienyl-Functionalized Pyrazolylborate Ligand.Structures of [Li_2(THF)3B(3-Mepz)3(C_5Me4)]and [K_2(THF)_2B(3-Mepz)_3(C_5Me_4)] [J] . Dmitrii Roitershtein, Angela Domingos, Noemia Marques Organometallics . 2004,第14期

机译：四甲基环戊二烯基官能化的吡唑基硼酸酯配体的碱金属配合物。[Li_2（THF）3B（3-Mepz）3（C_5Me4）]和[K_2（THF）_2B（3-Mepz）_3（C_5Me_4）的结构
4. New Complexes of Alkali-Metals as Precursors for MOCVD of Ferroelectric (K, Na)NbO_3 Thin Films [C] . D. M. Tsymbarenko, I. E. Korsakov, A. S. Mankevich, EuroCVD 17/CVD 17 . 2009

机译：新型碱金属金属配合物作为铁电（K，Na）NbO_3薄膜MOCVD的前体
5. MANGANESE(II) AND COBALT(III) COMPLEXES OF MULTIDENTATE LIGANDS: I. MANGANESE(II) COMPLEXES OF A MACROCYCLIC PENTADENTATE LIGAND. II. COBALT(III) COMPLEXES OF LINEAR TETRAMINE LIGANDS. [D] . HAMILTON, HOBART GORDON, JR. 1968

机译：多齿配体的锰（II）和钴（III）配合物：I.大环戊二烯配体的锰（II）配合物。二。线性叔丁胺配体的钴（III）配合物。
6. Hydrolysis of Methionine- and Histidine-Containing Peptides Promoted by Dinuclear Platinum(II) Complexes with Benzodiazines as Bridging Ligands: Influence of Ligand Structure on the Catalytic Ability of Platinum(II) Complexes [O] . Snežana Rajković, Beata Warżajtis, Marija D. Živković, 2018

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7. Rhodium and Iridium Complexes with the 1-(2-(Dimethylamino)ethyl)-2,3,4,5-tetramethylcyclopentadienyl Ligand [O] . Peter Jutzi, Marc O. Kristen, Beate Neumann, 1994

机译：用1-（2-（二甲基氨基）乙基）-2,3,4,5-四甲基环戊二烯基配体的铑和铱配合物
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 84. Carbarorane Tungsten Platinum Complexes having a MU-CC6H3ME(2)-2,6 Ligand: Crystal Structures of (WPt(MU- CC6H3ME(2)-2,6))(CO)N-(Pet3)(MU- [R] . Devore, D. D., Howard, J. A., Jeffery, J. C., 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分84.具有mU-CC6H3mE（2）-2,6配体的碳硼烷钨铂配合物：（Wpt（mU-CC6H3mE（2）-2,6））（CO）N-（pet3）（mU-）的晶体结构

Alkali-metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand

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