Synthesis, structure, luminescence, and electrochemical properties of polynuclear mercury(II) chalcogenolate complexes

摘要

A series of novel polynuclear mercury(II) diimine complexes with bridging chalcogenolate ligands have been synthesized and characterized and their luminescence and electrochemical properties studied. The crystal structures of [Hg(#mu#-SC_6H_4OCH_3-p)(bpy)]_n[PF_6]_n and [Hg(#mu#-SeC_6H_5)(bpy)]_n[PF_6]_n have also been determined (bpy = 2,2'-bipyridine).